Reductive cleavage of N,N′-di-tert-butyl­carbodi­imide generates tert-butyl­cyanamide ligands, (Me(3)CNCN)(−), that bind potassium both end-on and side-on in the same single crystal

N,N′-Di-tert-butyl­carbodi­imide, Me(3)CN=C=NCMe(3), undergoes reductive cleavage in the presence of the Gd(II) complex, [K(18-crown-6)(2)][Gd(II)(NR (2))(3)] (R = SiMe(3)), to form a new type of ligand, the tert-butyl­cyanamide anion, (Me(3)CNCN)(−). This new ligand can bind metals with one or two...

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Detalles Bibliográficos
Autores principales: Chung, Amanda B., Ziller, Joseph W., Evans, William J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336795/
https://www.ncbi.nlm.nih.gov/pubmed/32695450
http://dx.doi.org/10.1107/S205698902000732X

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336795/
https://www.ncbi.nlm.nih.gov/pubmed/32695450
http://dx.doi.org/10.1107/S205698902000732X

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