Comparison of two Mn(IV)Mn(IV)-bis-μ-oxo complexes {[Mn(IV)(N(4)(6-Me-DPEN))](2)(μ-O)(2)}(2+) and {[Mn(IV)(N(4)(6-Me-DPPN))](2)(μ-O)(2)}(2+)

The addition of tert-butyl hydro­peroxide ((t)BuOOH) to two structurally related Mn(II) complexes containing N,N-bis­(6-methyl-2-pyridyl­meth­yl)ethane-1,2-di­amine (6-Me-DPEN) and N,N-bis­(6-methyl-2-pyridyl­meth­yl)propane-1,2-di­amine (6-Me-DPPN) results in the formation of high-valent bis-oxo co...

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Detalles Bibliográficos
Autores principales: Coggins, Michael K., Downing, Alexandra N., Kaminsky, Werner, Kovacs, Julie A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336796/
https://www.ncbi.nlm.nih.gov/pubmed/32695449
http://dx.doi.org/10.1107/S2056989020004557

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336796/
https://www.ncbi.nlm.nih.gov/pubmed/32695449
http://dx.doi.org/10.1107/S2056989020004557

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