Crystal structure of {μ(2)-1,2-bis­[(4-methyl­phenyl­sulfan­yl]-3-oxoprop-1-ene-1,3-di­yl-1:2κ(2) C (3):C (1)}dicarbon­yl-1κ(2) C-[μ(2)-methyl­enebis(di­phenyl­phos­phane)-1:2κ(2) P:P′](tri­phenyl­phosphane-2κP)iron­platinum(Fe—Pt), [(OC)(2)Fe(μ-dppm){μ-C(=O)C(4-MeC(6)H(4)SCH(2))=CCH(2)SC(6)H(4)Me-4}Pt(PPh(3))]

The title compound, [FePt(C(19)H(18)OS(2))(C(18)H(15)P)(C(25)H(22)P(2))(CO)(2)], 1, [(OC)(2)Fe(μ-dppm)(μ-C(=O)C(CH(2)SC(6)H(4)Me-4)=CCH(2)SC(6)H(4)Me-4)Pt(PPh(3))], represents the first example of a diphosphane-bridged heterobimetallic Fe—Pt dimetalla­cyclo­pentenone complex resulting from a bimetal...

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Detalles Bibliográficos
Autores principales: Mohamed, Ahmed Said, Jourdain, Isabelle, Knorr, Michael, Brieger, Lukas, Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336804/
https://www.ncbi.nlm.nih.gov/pubmed/32695457
http://dx.doi.org/10.1107/S2056989020007859

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336804/
https://www.ncbi.nlm.nih.gov/pubmed/32695457
http://dx.doi.org/10.1107/S2056989020007859

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