Crystal structure of {μ(2)-1,2-bis­[(4-methyl­phenyl­sulfan­yl]-3-oxoprop-1-ene-1,3-di­yl-1:2κ(2) C (3):C (1)}dicarbon­yl-1κ(2) C-[μ(2)-methyl­enebis(di­phenyl­phos­phane)-1:2κ(2) P:P′](tri­phenyl­phosphane-2κP)iron­platinum(Fe—Pt), [(OC)(2)Fe(μ-dppm){μ-C(=O)C(4-MeC(6)H(4)SCH(2))=CCH(2)SC(6)H(4)Me-4}Pt(PPh(3))]

The title compound, [FePt(C(19)H(18)OS(2))(C(18)H(15)P)(C(25)H(22)P(2))(CO)(2)], 1, [(OC)(2)Fe(μ-dppm)(μ-C(=O)C(CH(2)SC(6)H(4)Me-4)=CCH(2)SC(6)H(4)Me-4)Pt(PPh(3))], represents the first example of a diphosphane-bridged heterobimetallic Fe—Pt dimetalla­cyclo­pentenone complex resulting from a bimetal...

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Autores principales: Mohamed, Ahmed Said, Jourdain, Isabelle, Knorr, Michael, Brieger, Lukas, Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336804/
https://www.ncbi.nlm.nih.gov/pubmed/32695457
http://dx.doi.org/10.1107/S2056989020007859
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author Mohamed, Ahmed Said
Jourdain, Isabelle
Knorr, Michael
Brieger, Lukas
Strohmann, Carsten
author_facet Mohamed, Ahmed Said
Jourdain, Isabelle
Knorr, Michael
Brieger, Lukas
Strohmann, Carsten
author_sort Mohamed, Ahmed Said
collection PubMed
description The title compound, [FePt(C(19)H(18)OS(2))(C(18)H(15)P)(C(25)H(22)P(2))(CO)(2)], 1, [(OC)(2)Fe(μ-dppm)(μ-C(=O)C(CH(2)SC(6)H(4)Me-4)=CCH(2)SC(6)H(4)Me-4)Pt(PPh(3))], represents the first example of a diphosphane-bridged heterobimetallic Fe—Pt dimetalla­cyclo­pentenone complex resulting from a bimetallic activation of metal-coordinated carbonyl ligand with an inter­nal alkyne, namely 1,4-bis­(p-tolyl­thio)­but-2-yne. The bridging μ(2)-C(=O)C(CH(2)SC(6)H(4)Me-4)=CCH(2)SC(6)H(4)Me-4 unit (stemming from a carbon–carbon coupling reaction between CO and the triple bond of the alkyne di­thio­ether) forms a five-membered dimetalla­cyclo­pentenone ring, in which the C=C bond is π-coordinated to the Fe center. The latter is connected to the Pt center through a short metal–metal bond of 2.5697 (6) Å.
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spelling pubmed-73368042020-07-20 Crystal structure of {μ(2)-1,2-bis­[(4-methyl­phenyl­sulfan­yl]-3-oxoprop-1-ene-1,3-di­yl-1:2κ(2) C (3):C (1)}dicarbon­yl-1κ(2) C-[μ(2)-methyl­enebis(di­phenyl­phos­phane)-1:2κ(2) P:P′](tri­phenyl­phosphane-2κP)iron­platinum(Fe—Pt), [(OC)(2)Fe(μ-dppm){μ-C(=O)C(4-MeC(6)H(4)SCH(2))=CCH(2)SC(6)H(4)Me-4}Pt(PPh(3))] Mohamed, Ahmed Said Jourdain, Isabelle Knorr, Michael Brieger, Lukas Strohmann, Carsten Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [FePt(C(19)H(18)OS(2))(C(18)H(15)P)(C(25)H(22)P(2))(CO)(2)], 1, [(OC)(2)Fe(μ-dppm)(μ-C(=O)C(CH(2)SC(6)H(4)Me-4)=CCH(2)SC(6)H(4)Me-4)Pt(PPh(3))], represents the first example of a diphosphane-bridged heterobimetallic Fe—Pt dimetalla­cyclo­pentenone complex resulting from a bimetallic activation of metal-coordinated carbonyl ligand with an inter­nal alkyne, namely 1,4-bis­(p-tolyl­thio)­but-2-yne. The bridging μ(2)-C(=O)C(CH(2)SC(6)H(4)Me-4)=CCH(2)SC(6)H(4)Me-4 unit (stemming from a carbon–carbon coupling reaction between CO and the triple bond of the alkyne di­thio­ether) forms a five-membered dimetalla­cyclo­pentenone ring, in which the C=C bond is π-coordinated to the Fe center. The latter is connected to the Pt center through a short metal–metal bond of 2.5697 (6) Å. International Union of Crystallography 2020-06-16 /pmc/articles/PMC7336804/ /pubmed/32695457 http://dx.doi.org/10.1107/S2056989020007859 Text en © Mohamed et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Mohamed, Ahmed Said
Jourdain, Isabelle
Knorr, Michael
Brieger, Lukas
Strohmann, Carsten
Crystal structure of {μ(2)-1,2-bis­[(4-methyl­phenyl­sulfan­yl]-3-oxoprop-1-ene-1,3-di­yl-1:2κ(2) C (3):C (1)}dicarbon­yl-1κ(2) C-[μ(2)-methyl­enebis(di­phenyl­phos­phane)-1:2κ(2) P:P′](tri­phenyl­phosphane-2κP)iron­platinum(Fe—Pt), [(OC)(2)Fe(μ-dppm){μ-C(=O)C(4-MeC(6)H(4)SCH(2))=CCH(2)SC(6)H(4)Me-4}Pt(PPh(3))]
title Crystal structure of {μ(2)-1,2-bis­[(4-methyl­phenyl­sulfan­yl]-3-oxoprop-1-ene-1,3-di­yl-1:2κ(2) C (3):C (1)}dicarbon­yl-1κ(2) C-[μ(2)-methyl­enebis(di­phenyl­phos­phane)-1:2κ(2) P:P′](tri­phenyl­phosphane-2κP)iron­platinum(Fe—Pt), [(OC)(2)Fe(μ-dppm){μ-C(=O)C(4-MeC(6)H(4)SCH(2))=CCH(2)SC(6)H(4)Me-4}Pt(PPh(3))]
title_full Crystal structure of {μ(2)-1,2-bis­[(4-methyl­phenyl­sulfan­yl]-3-oxoprop-1-ene-1,3-di­yl-1:2κ(2) C (3):C (1)}dicarbon­yl-1κ(2) C-[μ(2)-methyl­enebis(di­phenyl­phos­phane)-1:2κ(2) P:P′](tri­phenyl­phosphane-2κP)iron­platinum(Fe—Pt), [(OC)(2)Fe(μ-dppm){μ-C(=O)C(4-MeC(6)H(4)SCH(2))=CCH(2)SC(6)H(4)Me-4}Pt(PPh(3))]
title_fullStr Crystal structure of {μ(2)-1,2-bis­[(4-methyl­phenyl­sulfan­yl]-3-oxoprop-1-ene-1,3-di­yl-1:2κ(2) C (3):C (1)}dicarbon­yl-1κ(2) C-[μ(2)-methyl­enebis(di­phenyl­phos­phane)-1:2κ(2) P:P′](tri­phenyl­phosphane-2κP)iron­platinum(Fe—Pt), [(OC)(2)Fe(μ-dppm){μ-C(=O)C(4-MeC(6)H(4)SCH(2))=CCH(2)SC(6)H(4)Me-4}Pt(PPh(3))]
title_full_unstemmed Crystal structure of {μ(2)-1,2-bis­[(4-methyl­phenyl­sulfan­yl]-3-oxoprop-1-ene-1,3-di­yl-1:2κ(2) C (3):C (1)}dicarbon­yl-1κ(2) C-[μ(2)-methyl­enebis(di­phenyl­phos­phane)-1:2κ(2) P:P′](tri­phenyl­phosphane-2κP)iron­platinum(Fe—Pt), [(OC)(2)Fe(μ-dppm){μ-C(=O)C(4-MeC(6)H(4)SCH(2))=CCH(2)SC(6)H(4)Me-4}Pt(PPh(3))]
title_short Crystal structure of {μ(2)-1,2-bis­[(4-methyl­phenyl­sulfan­yl]-3-oxoprop-1-ene-1,3-di­yl-1:2κ(2) C (3):C (1)}dicarbon­yl-1κ(2) C-[μ(2)-methyl­enebis(di­phenyl­phos­phane)-1:2κ(2) P:P′](tri­phenyl­phosphane-2κP)iron­platinum(Fe—Pt), [(OC)(2)Fe(μ-dppm){μ-C(=O)C(4-MeC(6)H(4)SCH(2))=CCH(2)SC(6)H(4)Me-4}Pt(PPh(3))]
title_sort crystal structure of {μ(2)-1,2-bis­[(4-methyl­phenyl­sulfan­yl]-3-oxoprop-1-ene-1,3-di­yl-1:2κ(2) c (3):c (1)}dicarbon­yl-1κ(2) c-[μ(2)-methyl­enebis(di­phenyl­phos­phane)-1:2κ(2) p:p′](tri­phenyl­phosphane-2κp)iron­platinum(fe—pt), [(oc)(2)fe(μ-dppm){μ-c(=o)c(4-mec(6)h(4)sch(2))=cch(2)sc(6)h(4)me-4}pt(pph(3))]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336804/
https://www.ncbi.nlm.nih.gov/pubmed/32695457
http://dx.doi.org/10.1107/S2056989020007859
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