Cargando…
Crystal structure of {μ(2)-1,2-bis[(4-methylphenylsulfanyl]-3-oxoprop-1-ene-1,3-diyl-1:2κ(2) C (3):C (1)}dicarbonyl-1κ(2) C-[μ(2)-methylenebis(diphenylphosphane)-1:2κ(2) P:P′](triphenylphosphane-2κP)ironplatinum(Fe—Pt), [(OC)(2)Fe(μ-dppm){μ-C(=O)C(4-MeC(6)H(4)SCH(2))=CCH(2)SC(6)H(4)Me-4}Pt(PPh(3))]
The title compound, [FePt(C(19)H(18)OS(2))(C(18)H(15)P)(C(25)H(22)P(2))(CO)(2)], 1, [(OC)(2)Fe(μ-dppm)(μ-C(=O)C(CH(2)SC(6)H(4)Me-4)=CCH(2)SC(6)H(4)Me-4)Pt(PPh(3))], represents the first example of a diphosphane-bridged heterobimetallic Fe—Pt dimetallacyclopentenone complex resulting from a bimetal...
Autores principales: | Mohamed, Ahmed Said, Jourdain, Isabelle, Knorr, Michael, Brieger, Lukas, Strohmann, Carsten |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7336804/ https://www.ncbi.nlm.nih.gov/pubmed/32695457 http://dx.doi.org/10.1107/S2056989020007859 |
Ejemplares similares
-
Crystal structure of dicarbonyl[μ(2)-methylenebis(diphenylphosphane)-κ(2)
P:P′][μ(2)-2-(2,4,5-trimethylphenyl)-3-oxoprop-1-ene-1,3-diyl](triphenylphosphane-κP)ironplatinum(Fe—Pt)–dichloromethane–toluene (1/1/2), [(OC)(2)Fe(μ-dppm)(μ-C(=O)C(2,4,5-C(6)H(2)Me(3))=CH)Pt(PPh(3))]
por: Brieger, Lukas, et al.
Publicado: (2019) -
Heptacarbonyl-1κ(3)
C,2κ(4)
C-(4-phenylpyridine-1κN)di-μ-phenyltellurido-1:2κ(4)
Te:Te-dirhenium(I)
por: Vanitha, A., et al.
Publicado: (2010) -
trans-Di-μ-acetato-κ(4)
O:O′-bis[2-(5-phenylisoxazolin-3-yl)phenyl-κ(2)
C
(1),N]dipalladium(II)
por: Zhou, Jin, et al.
Publicado: (2008) -
[μ-1,6-Bis(diphenyphosphanyl)hexane-1:2κ(2)
P:P′]decacarbonyl-1κ(3)
C,2κ(3)
C,3κ(4)
C-triangulo-triruthenium(0)
por: Shawkataly, Omar bin, et al.
Publicado: (2012) -
Di-μ-chlorido-bis{[2-(morpholinomethyl)phenyl-κ(2)
C
(1),N]palladium(II)}
por: Copolovici, Dana, et al.
Publicado: (2008)