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Designing Homogeneous Copper-Free Sonogashira Reaction through a Prism of Pd–Pd Transmetalation

[Image: see text] Simultaneous introduction of two different palladium (pre)catalysts, one tuned to promote oxidative addition to (hetero)aryl bromide and another to activate terminal alkyne substrate, leads to productive Pd–Pd transmetalation, subsequent reductive elimination, and formation of disu...

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Detalles Bibliográficos
Autores principales: Martek, Bruno A., Gazvoda, Martin, Urankar, Damijana, Košmrlj, Janez
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7341530/
https://www.ncbi.nlm.nih.gov/pubmed/32379458
http://dx.doi.org/10.1021/acs.orglett.0c01227