Switchable Copper-Catalyzed Approach to Benzodithiole, Benzothiaselenole, and Dibenzodithiocine Skeletons

[Image: see text] A copper-catalyzed reaction between 2-bromo-benzothioamides and S(8) or Se involving sulfur rearrangement is reported, enabling access to benzodithioles 2 and benzothiaselenoles 6 in the presence of Cs(2)CO(3). In the absence of S(8) or Se, the reaction affords dibenzodithiocines 7...

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Detalles Bibliográficos
Autores principales: Huang, Meng-Qiao, Li, Tuan-Jie, Liu, Jian-Quan, Shatskiy, Andrey, Kärkäs, Markus D., Wang, Xiang-Shan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7343286/
https://www.ncbi.nlm.nih.gov/pubmed/32286077
http://dx.doi.org/10.1021/acs.orglett.0c00907

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7343286/
https://www.ncbi.nlm.nih.gov/pubmed/32286077
http://dx.doi.org/10.1021/acs.orglett.0c00907

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