Ni(I)–Alkyl Complexes Bearing Phenanthroline Ligands: Experimental Evidence for CO(2) Insertion at Ni(I) Centers

[Image: see text] Although the catalytic carboxylation of unactivated alkyl electrophiles has reached remarkable levels of sophistication, the intermediacy of (phenanthroline)Ni(I)–alkyl species—complexes proposed in numerous Ni-catalyzed reductive cross-coupling reactions—has been subject to specul...

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Detalles Bibliográficos
Autores principales: Somerville, Rosie J., Odena, Carlota, Obst, Marc F., Hazari, Nilay, Hopmann, Kathrin H., Martin, Ruben
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7351122/
https://www.ncbi.nlm.nih.gov/pubmed/32520556
http://dx.doi.org/10.1021/jacs.0c04695

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7351122/
https://www.ncbi.nlm.nih.gov/pubmed/32520556
http://dx.doi.org/10.1021/jacs.0c04695

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