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Ni(I)–Alkyl Complexes Bearing Phenanthroline Ligands: Experimental Evidence for CO(2) Insertion at Ni(I) Centers
[Image: see text] Although the catalytic carboxylation of unactivated alkyl electrophiles has reached remarkable levels of sophistication, the intermediacy of (phenanthroline)Ni(I)–alkyl species—complexes proposed in numerous Ni-catalyzed reductive cross-coupling reactions—has been subject to specul...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7351122/ https://www.ncbi.nlm.nih.gov/pubmed/32520556 http://dx.doi.org/10.1021/jacs.0c04695 |