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Visible Light Photocleavable Ruthenium-Based Molecular Gates to Reversibly Control Release from Mesoporous Silica Nanoparticles
Herein we present hybrid mesoporous silica nanomaterials (MSN) with visible light-sensitive ruthenium complexes acting as gates. Two different [Ru(bpy)(2)L1L2](2+) complexes were investigated by grafting [Ru(bpy)(2)(4AMP)(2)](PF(6))(2) (RC1) and [Ru(bpy)(2)(PPh(3))Cl]Cl (RC2) via two or one ligands...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7352806/ https://www.ncbi.nlm.nih.gov/pubmed/32481603 http://dx.doi.org/10.3390/nano10061030 |