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Assembling Polyiodides and Iodobismuthates Using a Template Effect of a Cyclic Diammonium Cation and Formation of a Low-Gap Hybrid Iodobismuthate with High Thermal Stability

Exploiting a template effect of 1,4-diazacycloheptane (also known as homopiperazine, Hpipe), four new hybrid iodides, (HpipeH(2))(2)Bi(2)I(10)·2H(2)O, (HpipeH(2))I(I(3)), (HpipeH(2))(3)I(6)·H(2)O, and (HpipeH(2))(3)(H(3)O)I(7), were prepared and their crystal structures were solved using single crys...

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Detalles Bibliográficos
Autores principales: Shestimerova, Tatiana A., Mironov, Andrei V., Bykov, Mikhail A., Grigorieva, Anastasia V., Wei, Zheng, Dikarev, Evgeny V., Shevelkov, Andrei V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7355432/
https://www.ncbi.nlm.nih.gov/pubmed/32549353
http://dx.doi.org/10.3390/molecules25122765