Enthalpies of Combustion and Formation of Severely Crowded Methyl-Substituted 1,3-dioxanes. The Magnitudes of 2,4- and 4,6-diaxial Me,Me-Interactions and the Chair–2,5-twist Energy Difference

Enthalpies of combustion of 2,2-trans-4,6- (1) and 4,4,6,6-tetramethyl- (2) and 2,4,4,6,6- (3) and 2,2,4,4,6-pentamethyl-1,3-dioxanes (4) were determined to estimate their enthalpies of formation in the gas phase. By comparing the latter with the corresponding enthalpies estimated based on the vario...

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Detalles Bibliográficos
Autores principales: Pihlaja, Kalevi, Kivelä, Henri, Vainiotalo, Pirjo, Steele, William V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7356987/
https://www.ncbi.nlm.nih.gov/pubmed/32549315
http://dx.doi.org/10.3390/molecules25122762

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7356987/
https://www.ncbi.nlm.nih.gov/pubmed/32549315
http://dx.doi.org/10.3390/molecules25122762

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