Thermodynamic Hydricity of Small Borane Clusters and Polyhedral closo-Boranes †

Thermodynamic hydricity (HDA(MeCN)) determined as Gibbs free energy (ΔG°[H](−)) of the H(−) detachment reaction in acetonitrile (MeCN) was assessed for 144 small borane clusters (up to 5 boron atoms), polyhedral closo-boranes dianions [B(n)H(n)](2−), and their lithium salts Li(2)[B(n)H(n)] (n = 5–17...

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Detalles Bibliográficos
Autores principales: Golub, Igor E., Filippov, Oleg A., Kulikova, Vasilisa A., Belkova, Natalia V., Epstein, Lina M., Shubina, Elena S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7357072/
https://www.ncbi.nlm.nih.gov/pubmed/32630429
http://dx.doi.org/10.3390/molecules25122920

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7357072/
https://www.ncbi.nlm.nih.gov/pubmed/32630429
http://dx.doi.org/10.3390/molecules25122920

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