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Synthesis of Ir(III) Hydrido Complexes by Oxidative Addition of Halogenated Theophylline and Adenine Derivatives
[Image: see text] The Ir(III) hydrido complexes [1] and [2] have been synthesized by the regioselective oxidative addition of the N7–H bond of 8-halogenotheophyllines to [IrCl(coe)(2)](2) in the presence of PPh(3). The use of dppf in this reaction yielded the bimetallic Ir(III)/Fe(II) hydrido comple...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7366355/ https://www.ncbi.nlm.nih.gov/pubmed/32685865 http://dx.doi.org/10.1021/acsomega.0c02290 |