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Understanding How the Rate of C–H Bond Cleavage Affects Formate Oxidation Catalysis by a Mo-Dependent Formate Dehydrogenase

[Image: see text] Metal-dependent formate dehydrogenases (FDHs) catalyze the reversible conversion of formate into CO(2), a proton, and two electrons. Kinetic studies of FDHs provide key insights into their mechanism of catalysis, relevant as a guide for the development of efficient electrocatalysts...

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Detalles Bibliográficos
Autores principales: Robinson, William E., Bassegoda, Arnau, Blaza, James N., Reisner, Erwin, Hirst, Judy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7366381/
https://www.ncbi.nlm.nih.gov/pubmed/32551568
http://dx.doi.org/10.1021/jacs.0c03574