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Understanding How the Rate of C–H Bond Cleavage Affects Formate Oxidation Catalysis by a Mo-Dependent Formate Dehydrogenase
[Image: see text] Metal-dependent formate dehydrogenases (FDHs) catalyze the reversible conversion of formate into CO(2), a proton, and two electrons. Kinetic studies of FDHs provide key insights into their mechanism of catalysis, relevant as a guide for the development of efficient electrocatalysts...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7366381/ https://www.ncbi.nlm.nih.gov/pubmed/32551568 http://dx.doi.org/10.1021/jacs.0c03574 |