Cargando…
Understanding How the Rate of C–H Bond Cleavage Affects Formate Oxidation Catalysis by a Mo-Dependent Formate Dehydrogenase
[Image: see text] Metal-dependent formate dehydrogenases (FDHs) catalyze the reversible conversion of formate into CO(2), a proton, and two electrons. Kinetic studies of FDHs provide key insights into their mechanism of catalysis, relevant as a guide for the development of efficient electrocatalysts...
Autores principales: | Robinson, William E., Bassegoda, Arnau, Blaza, James N., Reisner, Erwin, Hirst, Judy |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2020
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7366381/ https://www.ncbi.nlm.nih.gov/pubmed/32551568 http://dx.doi.org/10.1021/jacs.0c03574 |
Ejemplares similares
-
Oxidation-State-Dependent
Binding Properties of the
Active Site in a Mo-Containing Formate Dehydrogenase
por: Robinson, William E., et al.
Publicado: (2017) -
Reversible
and Selective Interconversion of Hydrogen
and Carbon Dioxide into Formate by a Semiartificial Formate Hydrogenlyase
Mimic
por: Sokol, Katarzyna P., et al.
Publicado: (2019) -
The mechanism of catalysis by type-II NADH:quinone oxidoreductases
por: Blaza, James N., et al.
Publicado: (2017) -
Interfacing Formate Dehydrogenase with Metal Oxides for the Reversible Electrocatalysis and Solar‐Driven Reduction of Carbon Dioxide
por: Miller, Melanie, et al.
Publicado: (2019) -
Tracking W-Formate Dehydrogenase Structural Changes During Catalysis and Enzyme Reoxidation
por: Vilela-Alves, Guilherme, et al.
Publicado: (2022)