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Mechanistic details of the cobalt-mediated dehydrogenative dimerization of aminoquinoline-directed benzamides

Key mechanistic features of the cobalt-mediated and aminoquinoline-directed dehydrogenative aryl–aryl coupling were investigated computationally and experimentally. A series of Co(II) and Co(III) complexes relevant to the proposed reaction cycle have been synthesized and characterized. Stoichiometri...

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Detalles Bibliográficos
Autores principales: Xu, Li-Ping, Liu, Elaine E. L.-N., Bacsa, John, MacBeth, Cora E., Musaev, Djamaladdin G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7366830/
https://www.ncbi.nlm.nih.gov/pubmed/32774827
http://dx.doi.org/10.1039/d0sc02066d