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Experimental Analyses Emphasize the Stability of the Meisenheimer Complex in a S(N)Ar Reaction Toward Trends in Reaction Pathways
The mechanism of S(N)Ar reactions between 2-chloro-5-nitropyrimidine with primary and secondary alicyclic amines, respectively, have been studied by kinetic measurements. The kinetic data obtained in aqueous media opens a controversial discussion based on Brönsted-type plots analysis. The first appr...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Frontiers Media S.A.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7366874/ https://www.ncbi.nlm.nih.gov/pubmed/32754575 http://dx.doi.org/10.3389/fchem.2020.00583 |