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Beyond Carbon: Enantioselective and Enantiospecific Reactions with Catalytically Generated Boryl- and Silylcopper Intermediates

[Image: see text] Catalytic asymmetric C–C bond formation with alkylcopper intermediates as carbon nucleophiles is now textbook chemistry. Related chemistry with boron and silicon nucleophiles where the boryl- and accordingly silylcopper intermediates are catalytically regenerated from bench-stable...

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Detalles Bibliográficos
Autores principales: Xue, Weichao, Oestreich, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7379128/
https://www.ncbi.nlm.nih.gov/pubmed/32724842
http://dx.doi.org/10.1021/acscentsci.0c00738