Nonclassical Mechanism in the Cyclodehydration of Diols Catalyzed by a Bifunctional Iridium Complex

1,4‐ and 1,5‐diols undergo cyclodehydration upon treatment with cationic N‐heterocyclic carbene (NHC)–Ir(III) complexes to give tetrahydrofurans and tetrahydropyrans, respectively. The mechanism was investigated, and a metal‐hydride‐driven pathway was proposed for all substrates, except for very ele...

Descripción completa

Detalles Bibliográficos
Autores principales: González Miera, Greco, Bermejo López, Aitor, Martínez‐Castro, Elisa, Norrby, Per‐Ola, Martín‐Matute, Belén
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7379557/
https://www.ncbi.nlm.nih.gov/pubmed/30475410
http://dx.doi.org/10.1002/chem.201805460

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7379557/
https://www.ncbi.nlm.nih.gov/pubmed/30475410
http://dx.doi.org/10.1002/chem.201805460

Ejemplares similares