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Nonclassical Mechanism in the Cyclodehydration of Diols Catalyzed by a Bifunctional Iridium Complex

1,4‐ and 1,5‐diols undergo cyclodehydration upon treatment with cationic N‐heterocyclic carbene (NHC)–Ir(III) complexes to give tetrahydrofurans and tetrahydropyrans, respectively. The mechanism was investigated, and a metal‐hydride‐driven pathway was proposed for all substrates, except for very ele...

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Detalles Bibliográficos
Autores principales:	González Miera, Greco, Bermejo López, Aitor, Martínez‐Castro, Elisa, Norrby, Per‐Ola, Martín‐Matute, Belén
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2019
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7379557/ https://www.ncbi.nlm.nih.gov/pubmed/30475410 http://dx.doi.org/10.1002/chem.201805460

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