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Syntheses and Molecular Structures of Liquid Pyrophoric Hydridosilanes

Trisilane, isotetrasilane, neopentasilane, and cyclohexasilane have been prepared in gram scale. In‐situ cryo crystallization of these pyrophoric liquids in sealed capillaries on the diffractometer allows access to the single crystal structures of these compounds. Structural parameters are discussed...

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Detalles Bibliográficos
Autores principales: Gerwig, Maik, Böhme, Uwe, Friebel, Mike, Gründler, Franziska, Franze, Georg, Rosenkranz, Marco, Schmidt, Horst, Kroke, Edwin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383127/
https://www.ncbi.nlm.nih.gov/pubmed/32728519
http://dx.doi.org/10.1002/open.202000152