Infrared Spectrum of the Adamantane(+)–Water Cation: Hydration‐Induced C−H Bond Activation and Free Internal Water Rotation

Diamondoid cations are reactive intermediates in their functionalization reactions in polar solution. Hydration is predicted to strongly activate their C−H bonds in initial proton abstraction reactions. To study the effects of microhydration on the properties of diamondoid cations, we characterize h...

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Detalles Bibliográficos
Autores principales: George, Martin Andreas Robert, Förstel, Marko, Dopfer, Otto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383494/
https://www.ncbi.nlm.nih.gov/pubmed/32392402
http://dx.doi.org/10.1002/anie.202003637

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383494/
https://www.ncbi.nlm.nih.gov/pubmed/32392402
http://dx.doi.org/10.1002/anie.202003637

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