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Infrared Spectrum of the Adamantane(+)–Water Cation: Hydration‐Induced C−H Bond Activation and Free Internal Water Rotation
Diamondoid cations are reactive intermediates in their functionalization reactions in polar solution. Hydration is predicted to strongly activate their C−H bonds in initial proton abstraction reactions. To study the effects of microhydration on the properties of diamondoid cations, we characterize h...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383494/ https://www.ncbi.nlm.nih.gov/pubmed/32392402 http://dx.doi.org/10.1002/anie.202003637 |