Ionic Dissociation of SiCl(4): Formation of [SiL(6)]Cl(4) with L=Dimethylphosphinic Acid

Reactions of SiCl(4) with R(2)PO(OH) (R=Me, Cl) yield compounds with six‐fold coordinated silicon atoms. Whereas R=Me afforded the hexacoordinated tetra‐cationic silicon complex [Si(Me(2)PO(OH))(6)](4+) with chloride counter‐ions, R=Cl caused release of HCl with formation of a cyclic dimeric silicon...

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Detalles Bibliográficos
Autores principales: Kowalke, Janine, Wagler, Jörg, Viehweger, Christine, Brendler, Erica, Kroke, Edwin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383495/
https://www.ncbi.nlm.nih.gov/pubmed/32511798
http://dx.doi.org/10.1002/chem.202000435

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383495/
https://www.ncbi.nlm.nih.gov/pubmed/32511798
http://dx.doi.org/10.1002/chem.202000435

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