Ionic Dissociation of SiCl(4): Formation of [SiL(6)]Cl(4) with L=Dimethylphosphinic Acid

Reactions of SiCl(4) with R(2)PO(OH) (R=Me, Cl) yield compounds with six‐fold coordinated silicon atoms. Whereas R=Me afforded the hexacoordinated tetra‐cationic silicon complex [Si(Me(2)PO(OH))(6)](4+) with chloride counter‐ions, R=Cl caused release of HCl with formation of a cyclic dimeric silicon...

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Detalles Bibliográficos
Autores principales: Kowalke, Janine, Wagler, Jörg, Viehweger, Christine, Brendler, Erica, Kroke, Edwin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383495/
https://www.ncbi.nlm.nih.gov/pubmed/32511798
http://dx.doi.org/10.1002/chem.202000435
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author Kowalke, Janine
Wagler, Jörg
Viehweger, Christine
Brendler, Erica
Kroke, Edwin
author_facet Kowalke, Janine
Wagler, Jörg
Viehweger, Christine
Brendler, Erica
Kroke, Edwin
author_sort Kowalke, Janine
collection PubMed
description Reactions of SiCl(4) with R(2)PO(OH) (R=Me, Cl) yield compounds with six‐fold coordinated silicon atoms. Whereas R=Me afforded the hexacoordinated tetra‐cationic silicon complex [Si(Me(2)PO(OH))(6)](4+) with chloride counter‐ions, R=Cl caused release of HCl with formation of a cyclic dimeric silicon complex [Si(Cl(2)PO(OH))(Cl(2)PO(2))(3)(μ‐Cl(2)PO(2))](2) with bridging bidentate dichlorophosphates.
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spelling pubmed-73834952020-07-27 Ionic Dissociation of SiCl(4): Formation of [SiL(6)]Cl(4) with L=Dimethylphosphinic Acid Kowalke, Janine Wagler, Jörg Viehweger, Christine Brendler, Erica Kroke, Edwin Chemistry Communications Reactions of SiCl(4) with R(2)PO(OH) (R=Me, Cl) yield compounds with six‐fold coordinated silicon atoms. Whereas R=Me afforded the hexacoordinated tetra‐cationic silicon complex [Si(Me(2)PO(OH))(6)](4+) with chloride counter‐ions, R=Cl caused release of HCl with formation of a cyclic dimeric silicon complex [Si(Cl(2)PO(OH))(Cl(2)PO(2))(3)(μ‐Cl(2)PO(2))](2) with bridging bidentate dichlorophosphates. John Wiley and Sons Inc. 2020-06-08 2020-06-26 /pmc/articles/PMC7383495/ /pubmed/32511798 http://dx.doi.org/10.1002/chem.202000435 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Communications
Kowalke, Janine
Wagler, Jörg
Viehweger, Christine
Brendler, Erica
Kroke, Edwin
Ionic Dissociation of SiCl(4): Formation of [SiL(6)]Cl(4) with L=Dimethylphosphinic Acid
title Ionic Dissociation of SiCl(4): Formation of [SiL(6)]Cl(4) with L=Dimethylphosphinic Acid
title_full Ionic Dissociation of SiCl(4): Formation of [SiL(6)]Cl(4) with L=Dimethylphosphinic Acid
title_fullStr Ionic Dissociation of SiCl(4): Formation of [SiL(6)]Cl(4) with L=Dimethylphosphinic Acid
title_full_unstemmed Ionic Dissociation of SiCl(4): Formation of [SiL(6)]Cl(4) with L=Dimethylphosphinic Acid
title_short Ionic Dissociation of SiCl(4): Formation of [SiL(6)]Cl(4) with L=Dimethylphosphinic Acid
title_sort ionic dissociation of sicl(4): formation of [sil(6)]cl(4) with l=dimethylphosphinic acid
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383495/
https://www.ncbi.nlm.nih.gov/pubmed/32511798
http://dx.doi.org/10.1002/chem.202000435
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