Cargando…

Ionic Dissociation of SiCl(4): Formation of [SiL(6)]Cl(4) with L=Dimethylphosphinic Acid

Reactions of SiCl(4) with R(2)PO(OH) (R=Me, Cl) yield compounds with six‐fold coordinated silicon atoms. Whereas R=Me afforded the hexacoordinated tetra‐cationic silicon complex [Si(Me(2)PO(OH))(6)](4+) with chloride counter‐ions, R=Cl caused release of HCl with formation of a cyclic dimeric silicon...

Descripción completa

Detalles Bibliográficos
Autores principales:	Kowalke, Janine, Wagler, Jörg, Viehweger, Christine, Brendler, Erica, Kroke, Edwin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383495/ https://www.ncbi.nlm.nih.gov/pubmed/32511798 http://dx.doi.org/10.1002/chem.202000435

Ejemplares similares

Effect of the SiCl(4) Flow Rate on SiBN Deposition Kinetics in SiCl(4)-BCl(3)-NH(3)-H(2)-Ar Environment
por: Li, Jianping, et al.
Publicado: (2017)

Effective silicon production from SiCl(4) source using hydrogen radicals generated and transported at atmospheric pressure
por: Okamoto, Yuji, et al.
Publicado: (2020)

A new pseudopolymorph of perchlorinated neopentasilane: the benzene monosolvate Si(SiCl(3))(4)·C(6)H(6)
por: Tillmann, Jan, et al.
Publicado: (2020)

Disilanes with Pentacoordinate Si Atoms by Carbon Dioxide Insertion into Aminodisilanes: Syntheses, Molecular Structures, and Dynamic Behavior
por: Ryll, Christopher, et al.
Publicado: (2022)

Identification of a SiCL1 gene controlling leaf curling and capsule indehiscence in sesame via cross-population association mapping and genomic variants screening
por: Zhang, Haiyang, et al.
Publicado: (2018)

A Non-Hydrolytic Sol–Gel Route to Organic-Inorganic Hybrid Polymers: Linearly Expanded Silica and Silsesquioxanes
por: Krupinski, Katrin, et al.
Publicado: (2023)

Pressure Dependence of Rate Coefficients of Unimolecular and Chemical Activation Reactions Connected to the Potential Energy Wells of Si(2)H(2)Cl(4), Si(2)Cl(6), and Si(2)Cl(4) via Rice–Ramsperger–Kassel–Marcus Calculations
por: Noda, Kaito, et al.
Publicado: (2022)

Behaviors in Ethylene Polymerization of MgCl(2)-SiO(2)/TiCl(4)/THF Ziegler-Natta Catalysts with Differently Treated SiO(2)
por: Senso, Nichapat, et al.
Publicado: (2011)

Synthesis of 1,1′-Bis(1-Methyl/Chloro-2,3,4,5-Tetraphenyl-1-Silacyclopentadienyl) [Ph(4)C(4)Si(Me/Cl)-(Me/Cl)SiC(4)Ph(4)] from Silole Anion [MeSiC(4)Ph(4)](−)•[Li(+) or Na(+)] and Silole Dianion [SiC(4)Ph(4)](2−)•2[Li(+)]; Oxidative Coupling of Silole Anion [MeSiC(4)Ph(4)](−)•[Li(+) or Na(+)] by Ferrous Chloride (FeCl(2)) and Oxidative Coupling and Chlorination of Silole Dianion [SiC(4)Ph(4)](2−)•2[Li(+)] by Cupric Chloride (CuCl(2))
por: Hong, Jang-Hwan
Publicado: (2019)

Effect of EtOH/MgCl(2) Molar Ratios on the Catalytic Properties of MgCl(2)-SiO(2)/TiCl(4) Ziegler-Natta Catalyst for Ethylene Polymerization
por: Patthamasang, Supanan, et al.
Publicado: (2011)

Biological Functions of the Novel Collectins CL-L1, CL-K1, and CL-P1
por: Ohtani, Katsuki, et al.
Publicado: (2012)

Li(6)SiO(4)Cl(2): A Hexagonal Argyrodite Based on Antiperovskite Layer Stacking
por: Morscher, Alexandra, et al.
Publicado: (2021)

Noble Metals Dissolution Catalyzed by [AlCl(4)(–)]-Based Ionic Liquids
por: Wang, Bolin, et al.
Publicado: (2023)

Ge–Cu-Complexes Ph(pyO)Ge(μ(2)-pyO)(2)CuCl and PhGe(μ(2)-pyO)(4)CuCl—Representatives of Cu(I)→Ge(IV) and Cu(II)→Ge(IV) Dative Bond Systems
por: Wagler, Jörg, et al.
Publicado: (2023)

On the interpretation of annual oscillations in (32)Si and (36)Cl decay rate measurements
por: Pommé, S., et al.
Publicado: (2021)

Nano-SnCl(4).SiO(2), an efficient catalyst for synthesis of benzimidazole drivatives as antifungal and cytotoxic agents
por: Zamani, Leila, et al.
Publicado: (2019)

Structural Analysis of the cl-Par-4 Tumor Suppressor as a Function of Ionic Environment
por: Raut, Krishna K., et al.
Publicado: (2021)

BIOELECTRIC POTENTIALS IN VALONIA : II. EFFECTS OF ARTIFICIAL SEA WATERS CONTAINING LiCl, CsCl, RbCl, OR NH(4)Cl
por: Damon, E. B.
Publicado: (1939)

Pyrosmalite-(Fe), Fe(8)Si(6)O(15)(OH,Cl)(10)
por: Yang, Hexiong, et al.
Publicado: (2011)

Defect-Mediated Atomic Layer Etching Processes on Cl–Si(100): An Atomistic Insight
por: Wang, Peizhi, et al.
Publicado: (2023)

Nanostructured Pt(NH(3))(4)Cl(2)/SiO(2) for nanomedicine: catalytic degradation of DNA in cancer cells
por: López, Tessy, et al.
Publicado: (2011)

Medium redshift clusters of galaxies: M/L in CL0017-20 and CL0500-24
por: Infante, L., et al.
Publicado: (1994)

Reaction of pharmacological active tris-(2-hydroxyethyl)ammonium 4-chlorophenylsulfanylacetate with ZnCl(2) or NiCl(2): first conversion of a protic ionic liquid into metallated ionic liquid
por: Mirskova, Anna N, et al.
Publicado: (2013)

Frequency of L-SIL and H-SIL Findings in HPV Positive Women
por: Asotic, Amir, et al.
Publicado: (2014)

LiYbCl(4)(THF)(4)
por: Richtera, Lukas, et al.
Publicado: (2011)

Efficient Synthesis of Furfural from Biomass Using SnCl(4) as Catalyst in Ionic Liquid
por: Nie, Yifan, et al.
Publicado: (2019)

Control of Ionic Conductivity by Lithium Distribution in Cubic Oxide Argyrodites Li(6+x)P(1–x)Si(x)O(5)Cl
por: Morscher, Alexandra, et al.
Publicado: (2022)

Synthesis of new hybrid pyridines catalyzed by Fe(3)O(4)@SiO(2)@urea-riched ligand/Ch-Cl
por: Zarei, Narges, et al.
Publicado: (2023)

Aluminum Patterned Electroplating from AlCl(3)–[EMIm]Cl Ionic Liquid towards Microsystems Application †
por: Al Farisi, Muhammad Salman, et al.
Publicado: (2018)

Tuning Philicity of Dichlorosilylene: Nucleophilic Behavior of the Dichlorosilylene–NHC Complex Cl(2)Si–IPr
por: Lee, Vladimir Ya., et al.
Publicado: (2019)

Reversible Cl/Cl(−) redox in a spinel Mn(3)O(4) electrode
por: Sandstrom, Sean K., et al.
Publicado: (2023)

Conductivity and Redox Potentials of Ionic Liquid Trihalogen Monoanions [X(3)](−), [XY(2)](−), and [BrF(4)](−) (X=Cl, Br, I and Y=Cl, Br)
por: Gully, Tyler A., et al.
Publicado: (2021)

Computational NMR Spectroscopy of Ionic Liquids: [C(4)C(1)im]Cl/Water Mixtures
por: Saielli, Giacomo
Publicado: (2020)

The Pseudo-Protic Ionic Liquids TOAH(+)Cl(−) and TODAH(+)Cl(−) as Carriers for Facilitated Transport of In(III) from HCl Solutions
por: Alguacil, Francisco José, et al.
Publicado: (2022)

Effect of NaCl road salt on the ionic composition of soils and Aesculus hippocastanum L. foliage and leaf damage intensity
por: Łuczak, Katarzyna, et al.
Publicado: (2021)

COMBINATION OF SALTS AND PROTEINS : III. THE COMBINATION OF CuCl(2), MgCl(2), CaCl(2), AlCl(3), LaCl(3), KCl, AgNO(3)AND Na(2)SO(4)WITH GELATIN.
por: Northrop, John H., et al.
Publicado: (1928)

Phenolic Compounds and Expression of 4CL Genes in Silver Birch Clones and Pt4CL1a Lines
por: Sutela, Suvi, et al.
Publicado: (2014)

Characterization of the Gh4CL gene family reveals a role of Gh4CL7 in drought tolerance
por: Sun, Shi-Chao, et al.
Publicado: (2020)

The Permeability and Selectivity of the Polyamide Reverse Osmosis Membrane were Significantly Enhanced by PhSiCl(3)
por: Yu, Junjie, et al.
Publicado: (2021)

Coincident Activation of Glutamate Receptors Enhances GABA(A) Receptor-Induced Ionic Plasticity of the Intracellular Cl(−)-Concentration in Dissociated Neuronal Cultures
por: Halbhuber, Lisa, et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_obkb7558mth8at8u1rnhik64sk