Cargando…
Nucleophilic Attack of Azide at Electrophilic Azides: Formation of N(6) Units in Hexazene and Aminopentazole Derivatives
With the help of selective (15)N labeling experiments, it has been confirmed that nucleophilic attack of azide at iminium‐activated organic azides leads to short‐lived hexazene intermediates. Such species do not only tend to a cleavage reaction with formation of N‐azido compounds, but also undergo r...
| Autores principales: | , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383498/ https://www.ncbi.nlm.nih.gov/pubmed/32212369 http://dx.doi.org/10.1002/anie.202003010 |