Strong and Confined Acids Control Five Stereogenic Centers in Catalytic Asymmetric Diels–Alder Reactions of Cyclohexadienones with Cyclopentadiene

We describe a highly enantioselective Diels–Alder reaction of cross‐conjugated cyclohexadienones with cyclopentadiene, in which five stereocenters are effectively controlled by a strongly acidic and confined imidodiphosphorimidate catalyst. Our approach provides tricyclic products in excellent stere...

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Detalles Bibliográficos
Autores principales: Ghosh, Santanu, Das, Sayantani, De, Chandra Kanta, Yepes, Diana, Neese, Frank, Bistoni, Giovanni, Leutzsch, Markus, List, Benjamin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383742/
https://www.ncbi.nlm.nih.gov/pubmed/32159921
http://dx.doi.org/10.1002/anie.202000307

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383742/
https://www.ncbi.nlm.nih.gov/pubmed/32159921
http://dx.doi.org/10.1002/anie.202000307

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