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Counter‐Intuitive Gas‐Phase Reactivities of [V(2)](+) and [V(2)O](+) towards CO(2) Reduction: Insight from Electronic Structure Calculations
[V(2)O](+) remains “invisible” in the thermal gas‐phase reaction of bare [V(2)](+) with CO(2) giving rise to [V(2)O(2)](+); this is because the [V(2)O](+) intermediate is being consumed more than 230 times faster than it is generated. However, the fleeting existence of [V(2)O](+) and its involvement...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383893/ https://www.ncbi.nlm.nih.gov/pubmed/32100908 http://dx.doi.org/10.1002/anie.202001223 |