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Autocatalytic Carbonyl Arylation through In Situ Release of Aryl Nucleophiles from N‐Aryl‐N′‐Silyldiazenes

A method for the catalytic generation of functionalized aryl alkali metals is reported. These highly reactive intermediates are liberated from silyl‐protected aryl‐substituted diazenes by the action of Lewis basic alkali metal silanolates, resulting in desilylation and loss of N(2). Catalytic quanti...

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Detalles Bibliográficos
Autores principales: Chauvier, Clément, Finck, Lucie, Irran, Elisabeth, Oestreich, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7383908/
https://www.ncbi.nlm.nih.gov/pubmed/32030857
http://dx.doi.org/10.1002/anie.201916004