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Reductive Deamination with Hydrosilanes Catalyzed by B(C(6)F(5))(3)
The strong boron Lewis acid tris(pentafluorophenyl)borane B(C(6)F(5))(3) is known to catalyze the dehydrogenative coupling of certain amines and hydrosilanes at elevated temperatures. At higher temperature, the dehydrogenation pathway competes with cleavage of the C−N bond and defunctionalization is...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7384015/ https://www.ncbi.nlm.nih.gov/pubmed/32311213 http://dx.doi.org/10.1002/anie.202004651 |