Cargando…

Reductive Deamination with Hydrosilanes Catalyzed by B(C(6)F(5))(3)

The strong boron Lewis acid tris(pentafluorophenyl)borane B(C(6)F(5))(3) is known to catalyze the dehydrogenative coupling of certain amines and hydrosilanes at elevated temperatures. At higher temperature, the dehydrogenation pathway competes with cleavage of the C−N bond and defunctionalization is...

Descripción completa

Detalles Bibliográficos
Autores principales:	Fang, Huaquan, Oestreich, Martin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7384015/ https://www.ncbi.nlm.nih.gov/pubmed/32311213 http://dx.doi.org/10.1002/anie.202004651

Ejemplares similares

Mechanistic insights into reductive deamination with hydrosilanes catalyzed by B(C(6)F(5))(3): A DFT study
por: Zhou, Miaomiao, et al.
Publicado: (2022)

Consecutive β,β′‐Selective C(sp(3))−H Silylation of Tertiary Amines with Dihydrosilanes Catalyzed by B(C(6)F(5))(3)
por: Fang, Huaquan, et al.
Publicado: (2021)

Stereospecific and Chemoselective Copper‐Catalyzed Deaminative Silylation of Benzylic Ammonium Triflates
por: Scharfbier, Jonas, et al.
Publicado: (2019)

Unprecedent formation of methylsilylcarbonates from iridium-catalyzed reduction of CO(2) with hydrosilanes
por: Guzmán, Jefferson, et al.
Publicado: (2020)

Decarbonylative Transfer Hydrochlorination of Alkenes and Alkynes Based on a B(C(6)F(5))(3)‐Initiated Grob Fragmentation
por: Xie, Kaixue, et al.
Publicado: (2022)

Nickel‐Catalyzed, Reductive C(sp(3))−Si Cross‐Coupling of α‐Cyano Alkyl Electrophiles and Chlorosilanes
por: Zhang, Liangliang, et al.
Publicado: (2021)

Silylium‐Ion‐Promoted (5+1) Cycloaddition of Aryl‐Substituted Vinylcyclopropanes and Hydrosilanes Involving Aryl Migration
por: He, Tao, et al.
Publicado: (2020)

Broad-spectrum kinetic resolution of alcohols enabled by Cu–H-catalysed dehydrogenative coupling with hydrosilanes
por: Dong, Xichang, et al.
Publicado: (2017)

Palladium-catalyzed tandem allylic substitution/cyclization and cascade hydrosilylated reduction: the influence of reaction parameters and hydrosilanes on the stereoselectivity
por: Long, Peng-Wei, et al.
Publicado: (2018)

The Cyclohexa‐2,5‐dienyl Group as a Placeholder for Hydrogen: Organocatalytic Michael Addition of an Acetaldehyde Surrogate
por: Chen, Weiqiang, et al.
Publicado: (2020)

Enantio‐ and Regioconvergent Nickel‐Catalyzed C(sp(3))−C(sp(3)) Cross‐Coupling of Allylic Electrophiles Steered by a Silyl Group
por: Kranidiotis‐Hisatomi, Nektarios, et al.
Publicado: (2021)

Borohydride catalyzed redistribution reaction of hydrosilane and chlorosilane: a potential system for facile preparation of hydrochlorosilanes
por: Chen, Yi, et al.
Publicado: (2020)

Copper‐Catalyzed Enantio‐ and Diastereoselective Addition of Silicon Nucleophiles to 3,3‐Disubstituted Cyclopropenes
por: Zhang, Liangliang, et al.
Publicado: (2019)

Reductive Deamination by Benzyne for Deoxy Sugar Synthesis Through a Domino Reaction
por: Hwu, Jih Ru, et al.
Publicado: (2017)

Formylation or methylation: what determines the chemoselectivity of the reaction of amine, CO(2), and hydrosilane catalyzed by 1,3,2-diazaphospholene?
por: Lu, Yu, et al.
Publicado: (2017)

Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones
por: Romero, R. Martin, et al.
Publicado: (2022)

DNA cytosine and methylcytosine deamination by APOBEC3B: enhancing methylcytosine deamination by engineering APOBEC3B
por: Fu, Yang, et al.
Publicado: (2015)

Hydrosilane σ‐Adduct Intermediates in an Adaptive Zinc‐Catalyzed Cross‐dehydrocoupling of Si−H and O−H Bonds
por: Patnaik, Smita, et al.
Publicado: (2021)

Copper‐Catalyzed Highly Enantioselective Addition of a Silicon Nucleophile to 3‐Substituted 2H‐Azirines Using an Si−B Reagent
por: Zhao, Zhi‐Yuan, et al.
Publicado: (2023)

B(C(6)F(5))(3)-Catalyzed Direct C3 Alkylation of Indoles and Oxindoles
por: Basak, Shyam, et al.
Publicado: (2020)

B(C(6)F(5))(3)‐Catalyzed E‐Selective Isomerization of Alkenes
por: Kustiana, Betty A., et al.
Publicado: (2022)

Intramolecular Friedel–Crafts alkylation with a silylium-ion-activated cyclopropyl group: formation of tricyclic ring systems from benzyl-substituted vinylcyclopropanes and hydrosilanes
por: He, Tao, et al.
Publicado: (2020)

Lewis Acid Catalyzed Transfer Hydromethallylation for the Construction of Quaternary Carbon Centers
por: Walker, Johannes C. L., et al.
Publicado: (2019)

Copper amine oxidases catalyze the oxidative deamination and hydrolysis of cyclic imines
por: Nagakubo, Toshiki, et al.
Publicado: (2019)

Development of copper-catalyzed deaminative esterification using high-throughput experimentation
por: Shen, Yuning, et al.
Publicado: (2022)

Regioselective hydroesterification of alkenes and alkenylphenols utilizing CO(2) and hydrosilane
por: Wang, Meng-Meng, et al.
Publicado: (2023)

Electrochemical C–N bond activation for deaminative reductive coupling of Katritzky salts
por: Liu, Yeqing, et al.
Publicado: (2021)

Defunctionalisation catalysed by boron Lewis acids
por: Fang, Huaquan, et al.
Publicado: (2020)

Synthesis of Non‐Symmetric Azoarenes by Palladium‐Catalyzed Cross‐Coupling of Silicon‐Masked Diazenyl Anions and (Hetero)Aryl Halides
por: Finck, Lucie, et al.
Publicado: (2022)

Bio‐Inspired Deaminative Hydroxylation of Aminoheterocycles and Electron‐Deficient Anilines
por: Ghiazza, Clément, et al.
Publicado: (2022)

Mechanistic insight into B(C(6)F(5))(3) catalyzed imine reduction with PhSiH(3) under stoichiometric water conditions
por: He, Yunqing, et al.
Publicado: (2021)

Mechanism Insights into the Iridium(III)- and B(C(6)F(5))(3)-Catalyzed Reduction of CO(2) to the Formaldehyde Level with Tertiary Silanes
por: Guzmán, Jefferson, et al.
Publicado: (2022)

Organic Monolayers by B(C(6)F(5))(3)-Catalyzed Siloxanation of Oxidized Silicon Surfaces
por: Escorihuela, Jorge, et al.
Publicado: (2017)

Catalytic hydrogen atom transfer from hydrosilanes to vinylarenes for hydrosilylation and polymerization
por: Asgari, Parham, et al.
Publicado: (2019)

Ni-catalyzed deaminative cross-electrophile coupling of Katritzky salts with halides via C─N bond activation
por: Ni, Shengyang, et al.
Publicado: (2019)

N-Heterocyclic carbene-catalyzed deaminative cross-coupling of aldehydes with Katritzky pyridinium salts
por: Kim, Inwon, et al.
Publicado: (2020)

σ- versus π-Activation of Alkynyl Benzoates Using B(C(6)F(5))(3)
por: Bähr, Alexander, et al.
Publicado: (2015)

Deamination of 5-Methylcytosine Residues in Mammalian Cells
por: Gromenko, E.V., et al.
Publicado: (2009)

Catalyst‐Free Deaminative Functionalizations of Primary Amines by Photoinduced Single‐Electron Transfer
por: Wu, Jingjing, et al.
Publicado: (2019)

Native Amides as Enabling Vehicles for Forging sp(3)–sp(3) Architectures via Interrupted Deaminative Ni-Catalyzed Chain-Walking
por: Rodrigalvarez, Jesus, et al.
Publicado: (2023)

Cannot write session to /tmp/vufind_sessions/sess_6vn46qlndqicn3n2lq41pajgus