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One-pot synthesis of oxazolidinones and five-membered cyclic carbonates from epoxides and chlorosulfonyl isocyanate: theoretical evidence for an asynchronous concerted pathway

The one-pot reaction of chlorosulfonyl isocyanate (CSI) with epoxides having phenyl, benzyl and fused cyclic alkyl groups in different solvents under mild reaction conditions without additives and catalysts was studied. Oxazolidinones and five-membered cyclic carbonates were obtained in ratios close...

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Detalles Bibliográficos
Autores principales: Demir, Esra, Sari, Ozlem, Çetinkaya, Yasin, Atmaca, Ufuk, Sağ Erdem, Safiye, Çelik, Murat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7385335/
https://www.ncbi.nlm.nih.gov/pubmed/32765796
http://dx.doi.org/10.3762/bjoc.16.148