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Silver(I) Complexes of Two Flexible Bis‐phospholane Ligands: Metallamacrocycles, Polymeric Chains, and Metallacryptands

In a 2:2 reaction with silver(I) chloride or bromide, 1,5‐bis(1‐phospholano)pentane (1a) afforded frame‐like macrocyclic structures, with intra‐ (2, Cl) or intermolecular (3, Br) halido bridges. In contrast, 1,7‐bis(1‐phospholano)heptane (1b) formed coordination polymers 4a (Cl) and 4b (Br) with bri...

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Detalles Bibliográficos
Autores principales: Boar, Paul, Lönnecke, Peter, Hey‐Hawkins, Evamarie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7386914/
https://www.ncbi.nlm.nih.gov/pubmed/32742042
http://dx.doi.org/10.1002/zaac.202000001