Stabilisation of Exotic Tribromide (Br(3)(−)) Anions via Supramolecular Interaction with a Tosylated Macrocyclic Pyridinophane. A Serendipitous Case

Tetraaza-macrocyclic pyridinophane L-Ts, decorated with a p-toluenesulfonyl (tosyl; Ts) group, appear to be a useful tool to provide evidence on how the interplay of various supramolecular forces can help stabilise exotic anionic species such as tribromide (Br(3)(−)) anions. Indeed, crystals of (H(2...

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Detalles Bibliográficos
Autores principales: Martínez-Camarena, Álvaro, Savastano, Matteo, Bazzicalupi, Carla, Bianchi, Antonio, García-España, Enrique
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7396983/
https://www.ncbi.nlm.nih.gov/pubmed/32664239
http://dx.doi.org/10.3390/molecules25143155

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7396983/
https://www.ncbi.nlm.nih.gov/pubmed/32664239
http://dx.doi.org/10.3390/molecules25143155

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