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The role of porphyrin peripheral substituents in determining the reactivities of ferrous nitrosyl species
Ferrous nitrosyl {FeNO}(7) species is an intermediate common to the catalytic cycles of Cd(1)NiR and CcNiR, two heme-based nitrite reductases (NiR), and its reactivity varies dramatically in these enzymes. The former reduces NO(2)(–) to NO in the denitrification pathway while the latter reduces NO(2...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Royal Society of Chemistry
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7407271/ https://www.ncbi.nlm.nih.gov/pubmed/32832056 http://dx.doi.org/10.1039/d0sc01625j |