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Thiyl Radicals: Versatile Reactive Intermediates for Cyclization of Unsaturated Substrates

Sulfur centered radicals are widely employed in chemical synthesis, in particular for alkene and alkyne hydrothiolation towards thioether bioconjugates. The steadfast radical chain process that enables efficient hydrothiolation has been explored in the context of cascade reactions to furnish complex...

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Detalles Bibliográficos
Autores principales: Lynch, Dylan M., Scanlan, Eoin M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7412111/
https://www.ncbi.nlm.nih.gov/pubmed/32646036
http://dx.doi.org/10.3390/molecules25133094