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Stereodivergent Synthesis of Camphor-Derived Diamines and Their Application as Thiourea Organocatalysts

A series of 18 regio- and stereo-chemically diverse chiral non-racemic 1,2-, 1,3-, and 1,4-diamines have been synthesized from commercial (1S)-(+)-ketopinic acid and (1S)-(+)-10-camphorsulfonic acid. The structures of the diamines are all based on the d-(+)-camphor scaffold and feature isomeric dive...

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Detalles Bibliográficos
Autores principales: Ričko, Sebastijan, Požgan, Franc, Štefane, Bogdan, Svete, Jurij, Golobič, Amalija, Grošelj, Uroš
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7412124/
https://www.ncbi.nlm.nih.gov/pubmed/32610466
http://dx.doi.org/10.3390/molecules25132978