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Selective preparation of tetrasubstituted fluoroalkenes by fluorine-directed oxetane ring-opening reactions
The selective ring-opening reaction of fluoroalkylidene-oxetanes was directed by the presence of the fluorine atom, enabling a two-step access to tetrasubstituted fluoroalkenes with excellent geometry control. Despite its small van der Waals radii electronic, rather than steric influences of the flu...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7418098/ https://www.ncbi.nlm.nih.gov/pubmed/32802210 http://dx.doi.org/10.3762/bjoc.16.160 |