Synergistic Ammonium (Hypo)Iodite/Imine Catalysis for the Asymmetric α-Hydroxylation of β-Ketoesters

[Image: see text] The synergistic use of chiral bifunctional ammonium iodide catalysts in combination with simple catalytically relevant aldimines allows for an unprecedented asymmetric α-hydroxylation reaction of β-ketoesters using H(2)O(2). The reaction proceeds via in situ formation of a hyperval...

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Detalles Bibliográficos
Autores principales: Mairhofer, Christopher, Novacek, Johanna, Waser, Mario
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7418104/
https://www.ncbi.nlm.nih.gov/pubmed/32706973
http://dx.doi.org/10.1021/acs.orglett.0c02198

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7418104/
https://www.ncbi.nlm.nih.gov/pubmed/32706973
http://dx.doi.org/10.1021/acs.orglett.0c02198

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