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Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria
Supported atomic metal sites have discrete molecular orbitals. Precise control over the energies of these sites is key to achieving novel reaction pathways with superior selectivity. Here, we achieve selective oxygen (O(2)) activation by utilising a framework of cerium (Ce) cations to reduce the ene...
Autores principales: | , , , , , , , , , , , , , , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7419315/ https://www.ncbi.nlm.nih.gov/pubmed/32782245 http://dx.doi.org/10.1038/s41467-020-17852-8 |