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Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria

Supported atomic metal sites have discrete molecular orbitals. Precise control over the energies of these sites is key to achieving novel reaction pathways with superior selectivity. Here, we achieve selective oxygen (O(2)) activation by utilising a framework of cerium (Ce) cations to reduce the ene...

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Detalles Bibliográficos
Autores principales: Kang, Liqun, Wang, Bolun, Bing, Qiming, Zalibera, Michal, Büchel, Robert, Xu, Ruoyu, Wang, Qiming, Liu, Yiyun, Gianolio, Diego, Tang, Chiu C., Gibson, Emma K., Danaie, Mohsen, Allen, Christopher, Wu, Ke, Marlow, Sushila, Sun, Ling-dong, He, Qian, Guan, Shaoliang, Savitsky, Anton, Velasco-Vélez, Juan J., Callison, June, Kay, Christopher W. M., Pratsinis, Sotiris E., Lubitz, Wolfgang, Liu, Jing-yao, Wang, Feng Ryan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7419315/
https://www.ncbi.nlm.nih.gov/pubmed/32782245
http://dx.doi.org/10.1038/s41467-020-17852-8