Comparison of tetravalent cerium and terbium ions in a conserved, homoleptic imidophosphorane ligand field

A redox pair of Ce(4+) and Ce(3+) complexes has been prepared that is stabilized by the [(NP(1,2-bis-(t)Bu-diamidoethane)(NEt(2)))](1–) ligand. Since these complexes are isostructural to the recently reported isovalent terbium analogs, a detailed structural and spectroscopic comparative analysis was...

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Detalles Bibliográficos
Autores principales: Rice, Natalie T., Popov, Ivan A., Russo, Dominic R., Gompa, Thaige P., Ramanathan, Arun, Bacsa, John, Batista, Enrique R., Yang, Ping, La Pierre, Henry S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7422963/
https://www.ncbi.nlm.nih.gov/pubmed/32832060
http://dx.doi.org/10.1039/d0sc01414a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7422963/
https://www.ncbi.nlm.nih.gov/pubmed/32832060
http://dx.doi.org/10.1039/d0sc01414a

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