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Comparison of tetravalent cerium and terbium ions in a conserved, homoleptic imidophosphorane ligand field
A redox pair of Ce(4+) and Ce(3+) complexes has been prepared that is stabilized by the [(NP(1,2-bis-(t)Bu-diamidoethane)(NEt(2)))](1–) ligand. Since these complexes are isostructural to the recently reported isovalent terbium analogs, a detailed structural and spectroscopic comparative analysis was...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7422963/ https://www.ncbi.nlm.nih.gov/pubmed/32832060 http://dx.doi.org/10.1039/d0sc01414a |