Quinone methide dimers lacking labile hydrogen atoms are surprisingly excellent radical-trapping antioxidants

Hydrogen atom transfer (HAT) is the mechanism by which the vast majority of radical-trapping antioxidants (RTAs), such as hindered phenols, inhibit autoxidation. As such, at least one weak O–H bond is the key structural feature which underlies the reactivity of phenolic RTAs. We recently observed th...

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Detalles Bibliográficos
Autores principales: Raycroft, Mark A. R., Chauvin, Jean-Philippe R., Galliher, Matthew S., Romero, Kevin J., Stephenson, Corey R. J., Pratt, Derek A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7422964/
https://www.ncbi.nlm.nih.gov/pubmed/32832049
http://dx.doi.org/10.1039/d0sc02020f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7422964/
https://www.ncbi.nlm.nih.gov/pubmed/32832049
http://dx.doi.org/10.1039/d0sc02020f

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