Cargando…
Quinone methide dimers lacking labile hydrogen atoms are surprisingly excellent radical-trapping antioxidants
Hydrogen atom transfer (HAT) is the mechanism by which the vast majority of radical-trapping antioxidants (RTAs), such as hindered phenols, inhibit autoxidation. As such, at least one weak O–H bond is the key structural feature which underlies the reactivity of phenolic RTAs. We recently observed th...
Autores principales: | Raycroft, Mark A. R., Chauvin, Jean-Philippe R., Galliher, Matthew S., Romero, Kevin J., Stephenson, Corey R. J., Pratt, Derek A. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2020
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7422964/ https://www.ncbi.nlm.nih.gov/pubmed/32832049 http://dx.doi.org/10.1039/d0sc02020f |
Ejemplares similares
-
The Domestication of ortho-Quinone
Methides
por: Bai, Wen-Ju, et al.
Publicado: (2014) -
Electrophilic
Reactivities of Vinyl p-Quinone Methides
por: Eitzinger, Andreas, et al.
Publicado: (2020) -
The Emergence of Quinone Methides in Asymmetric Organocatalysis
por: Caruana, Lorenzo, et al.
Publicado: (2015) -
CF(3)‐Containing para‐Quinone Methides for Organic Synthesis
por: Winter, Michael, et al.
Publicado: (2020) -
Reactivities of Quinone Methides versus o-Quinones in Catecholamine Metabolism and Eumelanin Biosynthesis
por: Sugumaran, Manickam
Publicado: (2016)