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A complementary approach to conjugated N-acyliminium formation through photoredox-catalyzed intermolecular radical addition to allenamides and allencarbamates

An intermolecular radical addition, using photoredox catalysis, to allenamides and allencarbamates is reported. This transformation synthesizes N-acyl-N’-aryl-N,N’-allylaminals, and proceeds by a conjugated N-acyliminium intermediate that previously has principally been generated by electrophilic ac...

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Detalles Bibliográficos
Autores principales: Koleoso, Olusesan K, Turner, Matthew, Plasser, Felix, Kimber, Marc C
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7431758/
https://www.ncbi.nlm.nih.gov/pubmed/32831955
http://dx.doi.org/10.3762/bjoc.16.165