The Chiral 1:2 Adduct (S)(S)(S)(C)(−)(589)-Ethyl 2-Phenylbutyl Sulphide-Mercury (II) Chloride:(−)(589)[(S)(S)(S)(C)-Et(2-PhBu)S.(HgCl(2))(2)]. Stereoselective Synthesis, Asymmetric Oxidation, Crystal and Molecular Structure and Circular Dichroism Spectra

Optically active (−)(589)ethyl (S)-2-phenylbutyl thioether, (−)(S)(C)-Et(PhBu)S (I), and its new diastereoisomeric mercury (II) chloride adduct, 1:2, (−)[(S)(S)(S)(C)-Et(PhBu)S.(HgCl(2))(2)](2), (II) were stereoselectively synthesized; the absorbance (UV) and circular dichroism (CD) spectra were mea...

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Detalles Bibliográficos
Autores principales: Biscarini, Paolo, Bilotti, Ivano, Ferranti, Francesco, Bacchi, Alessia, Pelizzi, Giancarlo, Mikołajczyk, Marian, Drabowicz, Jozef
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7435776/
https://www.ncbi.nlm.nih.gov/pubmed/32727057
http://dx.doi.org/10.3390/molecules25153398

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7435776/
https://www.ncbi.nlm.nih.gov/pubmed/32727057
http://dx.doi.org/10.3390/molecules25153398

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