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Selective access to either a doubly boron-doped tetrabenzopentacene or an oxadiborepin from the same precursor

The well-known red emitter tetrabenzo[de,hi,op,st]pentacene (TBPA) has been transformed into a bright blue emitter (B(2)-TBPA; λ(em) = 472 nm; c-hexane) via substitutional doping with two boron atoms. In contrast to the electron-rich TBPA, which forms endo-peroxides with O(2) under daylight, the ben...

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Detalles Bibliográficos
Autores principales: Radtke, Julian, Schickedanz, Kai, Bamberg, Marcel, Menduti, Luigi, Schollmeyer, Dieter, Bolte, Michael, Lerner, Hans-Wolfram, Wagner, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7442282/
https://www.ncbi.nlm.nih.gov/pubmed/32874487
http://dx.doi.org/10.1039/c9sc03115d