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Selective access to either a doubly boron-doped tetrabenzopentacene or an oxadiborepin from the same precursor
The well-known red emitter tetrabenzo[de,hi,op,st]pentacene (TBPA) has been transformed into a bright blue emitter (B(2)-TBPA; λ(em) = 472 nm; c-hexane) via substitutional doping with two boron atoms. In contrast to the electron-rich TBPA, which forms endo-peroxides with O(2) under daylight, the ben...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7442282/ https://www.ncbi.nlm.nih.gov/pubmed/32874487 http://dx.doi.org/10.1039/c9sc03115d |